Publications

List of Grapperhaus publications also available through google scholar.

undergraduate co-authors denoted in italics

Most Recent

110. "Counterion Effects of Imidazolium Ionic Liquids for the Passivation of the NiOx–Perovskite Interface in Blade Coated Perovskite Solar Cells" Panta, R.; Chapagain, S.; Armstrong, P. J.; Druffel, T.; Grapperhaus ACS Appl. Eng. Mater. 2024, ASAP (10.1021/acsaem.4c02471).

109. "Expanding the solvent diversity and perovskite compatibility of SnO2 inks that are directly deposited on perovskite layers" Chapagain, S.; Armstrong, P. J.; Panta, R.; Acharya, N.; Druffel, T.; Grapperhaus iScience 2024, 27, 110964 (10.1016/j.isci.2024.110964).

108. "Prolonged Stability of Pb-Catalyzed CO2 Electroreduction to Methyl Formate in Acidic Methanol" Hofsommer, D. T.; Gautam, M.; Uttarwar, S. S.; Grapperhaus, C. A.; Spurgeon, J. M. ACS Appl. Eng. Mater. 2024, 6, 2624-2632 (10.1021/acsaem.3c00166)

107. "Modulating the reduction potential and ligand basicity of Ni(II) HER catalysts with highly conjugated N2S2 ligands" Paudel, M.; Karki, S.; Bajaj, K.; Hofsommer, D. H.; Parmar, S.; Mashuta, M. S.; Kozlowski, P. M.; Gupta, G.; Buchanan, R. M.; Grapperhaus, C. A. Inorg. Chim. Acta 2024, 572, 122254 (10.1016/j.ica.2024.122254)

106. "Enhancing CO2 Capture via Metal–Ligand Cooperativity: Tuning Ligand Basicity and Zn(II) Lewis Acidity" Phipps, C. A.; Zirilli, C. D.; Duff, B. G.; Erickson, J. D.; Karki, S.; Okolocha, C.; Mashuta, M. S.; Buchanan, R. M.; Grapperhaus, C. A. Inorg. Chem. 2024, 63, 9992-10000 (10.1021/acs.inorgchem.4c01159)

105. "Scalable Solution Processing of Cu:NiOx Nanoparticles for Perovskite Solar Cells" Armstrong, P. J.; Chapagain, S.; Panta, R.; Druffel, T.; Grapperhaus, C. A. ACS Appl. Energy Mater. 2024, 7, 3627-3634 (1 0.1021/acsaem.3c03103 )

104. "Electrochemical Conversion of CO2 to Ethyl Formate in Ethanol" Hofsommer, D. T.; Zamborini, I. R.; Uttarwar, S. S.; Phipps, C. A.; Gautam, M.; Nkurunziza, F.; Grapperhaus, C. A.; Spurgeon, J. M. ACS Sustainable Chem. Eng. 2024, 12, 882-892 (10.1021/acssuschemeng.3c05853)

103. "Two-Membrane Dual Non-Aqueous/Aqueous Electrolyte Flow Cell Operation for Electrochemical Conversion of CO2 to Methyl Formate" Gautam, M.; Nkurunziza, F.; Mulvehill, M. C.; Uttarwar, S. S.; Hofsommer, D. T.; Grapperhaus, C. A.; Spurgeon, J. M. ChemSusChem 2023, e202301337 (10.1002/cssc.202301337)

102. "Electrochemical CO2 Reduction Catalytic Activity and Materials Characterization of Heterogeneous Zinc Carbonaceous Layers Derived from a Zinc(II) Molecular Catalyst" Nkurunziza, F. ; Phipps, C. A.; Hofsommer, D. T.; Mulvehill, M. C.; Grapperhaus, C. A.; Spurgeon, J. M. ACS Appl. Energy Mat. 2023, 6,10432–10441 (10.1021/acsaem.01455b).

101. "Ligand and Linkage Isomers of Bis(ethylthiocarbamato)Copper Complexes with Cyclic C6H8 Backbone Substituents: Synthesis, Characterization, and Antiproliferation Activity" Bajaj, K.; Andres, S. A.; Hofsommer, D. T.; Michael, O. C.; Mashuta, M. S.; Bates, P. J.; Buchanan, R. M.; Grapperhaus, C. A. Eur. J. Inorg. Chem. 2023, e202300447 (10.1002/ejic.202300447).

100. "Synthesizing and formulating metal oxide nanoparticle inks for perovskite solar cells" Armstrong, P. J.; Chapagain, S.; Panta, R.; Grapperhaus, C.; Druffel, T. Chem. Comm. 2023,59, 12248-12261 (10.1039/d3cc02830e).

99. "Investigating BioCaRGOS, a Sol–Gel Matrix for the Stability of Heme Proteins under Enzymatic Degradation and Low pH" Potnis, C. S.; Grapperhaus, C. A. ; Gupta, G. ACS Omega 2023, 8, 32053-32059 (10.1021/acsomega.3c04012)

98. "Physical structure of constitutional isomers influences antiproliferation activity of thiosemicarbazone-alkylthiocarbamate copper complexes" Bajaj, K.; Andres, S. A.; Hofsommer, D. T.; Greene, A. F.; Hietsoi, O.; Mashuta, M. S.; Weis, T.; Beverly, L. J.; Bates, P. J.; Buchanan, R. M.; Grapperhaus, C. A. J. Inorg. Biochem. 2023, 246, 112288 (10.1016/j.jinorgbio.2023.112288).

97. "IPL-Annealed Mixed-Cation Perovskites with Robust Coating Window toward Scalable Manufacturing of Commercial Perovskite Solar Cells" Martin, B.; Chapagain, S.; Armstrong, P.; Grapperhaus, C. A.; Reese, M. O.; Druffel, T. ACS Appl. Energy Mater. 2023, 6, 5207-5216 (10.1021/acsaem.3c00134).

96. "High Performing Inverted Flexible Perovskite Solar Cells via Solution Phase Deposition of Yttrium-Doped SnO2 Directly on Perovskite" Chapagain, S.; Martin, B.; Armstrong, P.; Perkins, C. L.; Reese, M. O.; Druffel, T.; Grapperhaus, C. A. ACS Appl. Energy Mater. 2023, 6, 4496-4502 (10.1021/acsaem.2c03720). Highlighted in PV Magazine

95. "Prolonged Stability of Pb-Catalyzed CO2 Electroreduction to Methyl Formate in Acidic Methanol" Hofsommer, D. H.; Gautam, M.; Uttarwar, S. S.; Grapperhaus, C. A.; Spurgeon, J. M. ACS Appl. Energy Mater. 2023, 6, 2624-2632 (10.1021/acsaem.3c00166).

94. "Metal–Ligand Cooperativity Promotes Reversible Capture of Dilute CO2 as a Zn(II)-Methylcarbonate" Phipps, C. A.; Hofsommer, D. H.; Zirilli, C. D.; Duff, B. G.; Mashuta, M. S.; Buchanan, R. M.; Grapperhaus, C. A. Inorg. Chem. 2023, 62, 2751-2759 (10.1021.acs.inorgchem.2c03868).

93. "Rapid scalable fabrication of roll-to-roll slot-die coated flexible perovskite solar cells using intense pulse light annealing" Chandrasekhar, P. S.; Chapagain, S.; Blake, M.; Armstrong, P. J.; Grapperhaus, C. A.; Druffel, T. L. Sustain. Energy Fuels 2022, 6, 5316-5323 (10.1039/D2SE00911K).

92. "Enhancing the compatibility of BioCaRGOS silica sol-gel technology with ctDNA extraction and droplet digital PCR (ddPCR) analysis" Potnis, C. S.; Chauhan, R.; Kalbfleisch, T. S.; Alexander, E.; Eichhold, L.; Bansal, M.; Grapperhaus, C. A.; Linder, M. W.; Gupta, G. RSC Adv. 2022, 12, 29399-29404 (10.1039/D2RA05862F).

91. "Unravelling the Potential of Disposable and Modifiable Pencils as Catalyst Supports for Hydrogen Evolution Reaction" Paudel, M.; Daniels, B.; Arts, A. A.; Gupta, A.; Kalbfleisch, T.; Hofsommer, D. H.; Grapperhaus, C. A.; Buchanan, R. M.; Gupta, G. New J. Chem. 2022, 46, 18832-18838 (10.1039/D2NJ03359C).

90. "Comparative Technoeconomic Analysis of Pathways for Electrochemical Reduction of CO2 with Methanol to Produce Methyl Formate" Spurgeon, J. M., Theaker, N.; Phipps, C. A.; Uttarwar, S. S.; Grapperhaus, C. A. ACS Sustainable Chem. Eng. 2022, 38, 12882-12894 (10.1021/acssuschemeng.2c04362).

89. "The effect of flue gas contaminants on electrochemical reduction of CO2 to methyl formate in a dual methanol/water electrolysis system" Gautam, M.; Hofsommer, D. T.; Uttarwar, S. S.; Theaker, N.; Paxton, W. F.; Grapperhaus, C. A.; Spurgeon, J. M. Chem. Catalysis 2022, 2, 2664 - 2378 (10.1016/j.checat.2022.08.001).

88. "Ligand-Centered Hydrogen Evolution with Ni(II) and Pd(II)DMTH" Phipps, C. A.; Hofsommer, D. T.; Toda, M. J.; Nkurunziza, F.; Shah, B.; C. A; Spurgeon, J. M.; Kozlowski, P. M.; Buchanan, R. M.; Grapperhaus, C. A. Inorg. Chem. 2022, 61, 9792 - 9800 (10.1021/acs.inorgchem.2c01326).

87. "Investigations of Bis(alkylthiocarbamato) copper Linkage Isomers" Bajaj, K.; Andres, S. A.; Hofsommer, D. T.; Galib, M.; Mashuta, M. S.; Bennet B.; Narayanan, B.; Buchanan, R. M.; Bates, P. J.; Grapperhaus, C. A. Inorg. Chem. 2022, 61, 7715 - 7719 (10.1021/acs.inorgchem.2c00371).

86. "The pH and Potential Dependence of Pb-Catalyzed Electrochemical CO2 Reduction to Methyl Formate in a Dual Methanol/Water Electrolyte" Hofsommer, D. T.; Liang, Y.; Uttarwar, S. S.; Gautam, M.; Pishgar, S.; Gulati, S.; Grapperhaus, C. A; Spurgeon, J. M. ChemSusChem 2022, e202102289 (10.1002/cssc.202102289).

85. "Solvation of NiOx for hole transport layer deposition in perovskite solar cells" Armstrong, P.; Chandrasekhar, P. S.; Chapagain, S.; Cline, C. M.; F. A. M. van Hest, M.; Druffel, T.; Grapperhaus, C. A. Nanotechnology 2022, 33, 065403 (10.1088/1361-6528/ac328e).

84. "DNA-mediated hierarchical organization of gold nanoprisms into 3D aggregates and their application in surface-enhanced Raman scattering and fluorescence" Chowdhury, E.; Rahaman, M. S. S.; Sathitsuksanoh, N.; Grapperhaus, C.; O'Toole, M. Phys. Chem. Chem. Phys. 2021, 23, 25256-25263 (10.1039/D1CP03684J).

83. "Antifungal activity of thiosemicarbazones, bis(thiosemicarbazones), and their metal complexes" Bajaj, K.; Buchanan, R. M.; Grapperhaus, C. A. J. Inorg. Biochem. 2021, 225, 111620 (10.1016/j.jinorgbio.2021.111620).

82. "Direct Deposition of Nonaqueous SnO2 Dispersion by Blade Coating on Perovskites for the Scalable Fabrication of p–i–n Perovskite Solar Cells" Chapagain, S.; Chandrasekhar, P. S.; McGott, D.; Bramante, R. C.; F. A. M. van Hest, M.; Reese, M. O.; Druffel, T.; Grapperhaus, C. A. ACS Appl. Energy Matr. 2021, 4, 10477-10483 (10.1021/acsaem.1c01287).

81. "Copper bis(thiosemicarbazone) Complexes with Pendent Polyamines: Effects of Proton Relays and Charged Moieties on Electrocatalytic HER" Calvary, C. A.; Hietsoi, O.; Hofsommer, D. T.; Brun, H. C.; Costello, A. M.; Mashuta, M. S.; Spurgeon, J. M.; Buchanan, R. M.; Grapperhaus, C. A. Eur. J. Inorg. Chem., 2021, 2021, 267-275 (10.1002/ejic.202000774).

80. "Small molecule crystals with 1D water wires modulate electronic properties of surface water networks" Saraei, N.; Gupta, A. J.; Hietsoi, O.; Frye, B. C.; Hofsommer, D. T.; Sumanasekera, G.; Gupta, G.; Mashuta, M. S.; Buchanan, R. M.; Grapperhaus, C. A. Appl. Mater. Today 2021, 22, 100895 (10.1016/j.apmt.2020.100895).

79. "DNA-induced assembly of gold nanoprisms and polystyrene beads into 3D plasmonic SERS substrates" Chowdhury, E.; Rahaman, M. S.; Sathitsuksanoh, N.; Grapperhaus, C. A.; O'Toole, M. G. Nanotechnology 2021, 32, 025506 (10.1088/1361-6528/abbc22).

2016 - 2020

78. "Facet-selective asymmetric functionalization of anisotropic gold nanoprisms for Janus particle synthesis" Chowdhury, E.; Grapperhaus, C. A.; O'Toole, M. G. J. Nano. Res. 2020, 22, 142 ( 10.1007/s11051-020-04879-7).

77. "Exploiting Metal-Ligand Cooperativity to Sequester, Activate, and Reduce Atmospheric Carbon Dioxide with a Neutral Zinc Complex" Cronin, S. P.; Strain, J. M.; Mashuta, M. S.; Spurgeon, J. M.; Buchanan, R. M.; Grapperhaus, C. A. Inorg. Chem. 2020, 59, 4835-4841 (10.1021/acs.inorgchem.0c00121).

76. "Synthesis, Characterization, and Biological Activity of Hybrid Thiosemicarbazone-Alkylthiocarbamate Metal Complexes" Andres, S. A.; Bajaj, K.; Vishnosky, N. S.; Peterson, M. A., Mashuta, M. S.; Buchanan, R. M.; Bates, P. J.; Grapperhaus, C. A. Inorg. Chem. 2020, 59, 4924-4935 (10.1021/acs.inorgchem.0c00182).

75. "Electrocatalytic Hydrogen Evolution and Oxidation with Rhenium Tris(thiolate) Complexes: A Competition between Rhenium and Sulfur for Electrons and Protons" Tang, H.; Brothers, E. N. B.; Grapperhaus, C. A.; Hall, M. B. ACS Catal. 2020, 10, 3778-3789 (10.1021/acscatal.9b04579).

74. "Utilizing Charge Effects and Minimizing Intramolecular Proton Rearrangement to Improve Overpotential of a Thiosemicarbazonato Zinc HER Catalyst" Cronin, S. P.; Mamun, A. A.; Toda, M. J.; Mashuta, M. S.; Losovyj, Y.; Kozlowski, P. M.; Buchanan, R. M.; Grapperhaus, C. A. Inorg. Chem. 2019, 58, 12986-12997 (10.1021/acs.inorgchem.9b01912).

73. “Effect of Stacking Interactions on the Translation of Structurally Related Bis(thiosemicarbazonato)nickel(II) HER Catalysts to Modified Electrode Surfaces” Gupta, A. J.; Vishnosky, N. S.; Hietsoi, O.; Losovyj, Y.; Strain, J.; Spurgeon, J.; Mashuta, M. S.; Jain, R.; Buchanan, R. M.; Gupta, G.; Grapperhaus, C. A. Inorg. Chem. 2019, 58, 12025-12039 (10.1021/acs.inorgchem.9b01209).

72. “Synthesis, Characterization, and HER Activity of Pendant Diamine Derivatives of NiATSM” Diamine Derivatives of NiATSM” Calvary, C. A.; Hietsoi, O.; Strain, J. M.; Mashuta, M. S.; Spurgeon, J. M.; Buchanan, R. M.; Grapperhaus, C. A. Eur. J. Inorg. Chem. 2019, 3782-3790 (10.1002/ejic.201900721).

71. “Photocatalytic hydrogen evolution on Si photocathodes modified with bis(thiosemicarbazonato)nickel(II)/Nafion” Gulati, S.; Hietsoi, O.; Calvary, C. A.; Strain, J. M.; Pishgar, S.; Brun, H. C.; Grapperhaus, C. A.; Buchanan, R. M.; Spurgeon, J. M. Chem. Commun. 2019, 55, 9440-9443 (10.1039/c9cc04117f).

70. “Water wire clusters in isostructural Cu(II) and Ni(II) complexes: Synthesis, characterization, and thermal analysis” Saraei, N.; Hietsoi, O.; Frye, B. C.; Gupta, A. J.; Mashuta, M. S.; Gupta, G.; Buchanan, R. M.; Grapperhaus, C. A. Inorg. Chim. Acta 2019, 492, 268-274 (10.1016/j.ica.2019.04.012).

69. “Active uptake of hydrophilic copper complex Cu(II)-TETA in primary cultures of neonatal rat cardiomyocytes” Fu, C.; Lizhao, J.; Luo, Z.; Wang, T.; Grapperhaus C. A.; Ding, X.; Kang, Y. J. Metallomics 2019, 11, 565-575 (10.1039/C8MT00277K).

68. “Streams, cascades, and pools: various water cluster motifs in structurally similar Ni(II) complexes” Saraei, N.; Hietsoi, O.; Mullins, C. S.; Gupta, A. J.; Frye, B. C.; Mashuta, M. S.; Buchanan, R. M.; Grapperhaus C. A. CrystEngComm 2018, 20, 7071-7081 (10.1039/C8CE01153B).

67. “Ligand-Assisted Metal-Centered Electrocatalytic Hydrogen Evolution upon Reduction of a Bis (thiosemicarbazonato)Ni (II) Complex” Jain, R.; al Mamun, A.; Buchanan, R. M.; Kozlowski, P. M.; Grapperhaus C. A. Inorg. Chem. 2018, 57, 13486-13493 (10.1021/acs.inorgchem.8b02110).

66. “Metal-Assisted Ligand-Centered Electrocatalytic Hydrogen Evolution upon Reduction of a Bis(thiosemicarbazonato)Cu(II) Complex” Haddad, A. Z.; Cronin, S. P.; Mashuta, M. S.; Buchanan, R. M.; Grapperhaus, C. A. Inorg. Chem. 2017, 56 , 11254–11265 (10.1021/acs.inorgchem.7b01608).

65. "Electrocatalytic Hydrogen Evolution and Hydrogen Oxidation with a Ni(PS)2 Complex" Jain, R.; Mashuta, M. S.; Buchanan, R. M.; Grapperhaus C. A. Eur. J. Inorg. 2017, 2017, 3714-3719 (10.1002/ejic.201700590).

64. "Syntheses, structures, and electrochemical studies of N,N'-bis(alkylthiocarbamate)butane-2,3-diimine Cu(II) complexes as pendant alkoxy derivatives of Cu(ATSM)" Vishnosky, N. S.; Mashuta, M. S.; Buchanan, R. M.; Grapperhaus C. A. Inorg. Chim. Acta 2017, 416, 45-51 (10.1016/j.ica.2017.02.003).

63. "Translation of Ligand-Centered Hydrogen Evolution Reaction Activity and Mechanism of a Rhenium-Thiolate from Solution to Modified Electrodes: A Combined Experimental and Density Functional Theory Study" Zhang, W.; Haddad, A. Z.; Garabato, B. D.; Kozlowski, P. M.; Buchanan, R. M.; Grapperhaus C. A. Inorg. Chem., 2017, 56, 2177-2178 (10.1021/acs.inorgchem.6b02829).

62. "Copper catalysed aerobic oxidation of benzylic alcohols in an imidazole containing N4 ligand framewo" Jain, R.; Gibson, T. J.; Mashuta, M. S.; Buchanan, R. M.; Grapperhaus C. A. Dalton Trans., 2016, 45, 18356-18364 (10.1039/C6DT03395D).

61. "Reversible Methanol Addition to Copper Schiff Base Complexes: A Kinetic, Structural, and Spectroscopic Study of Reactions at Azomethine C=N Bonds" Zhang, W.; Saraei, N.; Hanlin, N.; Vaugh, J. R.; Jones, A. S.; Mashuta, M. S.; Buchanan, R. M.; Grapperhaus C. A. Dalton Trans., 2016, 45, 15791-15799 (10.1039/C6DT01955B).

60. "Beyond Metal-Hydrides: Non-Transition-Metal and Metal-Free Ligand-Centered Electrocatalytic Hydrogen Evolution and Hydrogen Oxidation" Haddad, A. Z.; Garabato, B. D.; Kozlowski, P. M.; Buchanan, R. M.; Grapperhaus, C. A. J. Am. Chem. Soc. 2016, 138, 7844-7847 (10.1021/jacs.6b04441).

2011 - 2015

59. "Proposed Ligand-Centered Electrocatalytic Hydrogen Evolution and Hydrogen Oxidation at a Noninnocent Mononuclear Metal-Thiolate" Haddad, A. Z.; Kumar, D.; Sampson, K. O.; Matzner, A. M.; Mashuta, M. S.; Grapperhaus, C. A. J. Am. Chem. Soc. 2015, 137, 9238-9241 (10.1021/jacs.5b05561).

58. "Metal-centered oxidation decreases nitrile hydration activity of bioinspired (N2S3)Ru-PPh3 precatalysts" Kumar, D.; Mashuta, M. S.; Grapperhaus, C. A. Inorg. Chem. Commun. 2015, 61, 197-199 (10.1016/j.inoche.2015.10.001).

57. "Chemiresistive metal-stabilized thiyl radical films as highly selective ethylene sensors" Chauhan, R.; Moreno, M.; Banda, D. M.; Zamborini, F. P.; Grapperhaus, C. A. RSC Adv. 2014, 4, 46787-46790 (Doi 10.1039/C4ra07560a).

56. "Kinetic Effects of Sulfur Oxidation on Catalytic Nitrile Hydration: Nitrile Hydratase Insights from Bioinspired Ruthenium(II) Complexes" Kumar, D.; Nguyen, T. N.; Grapperhaus, C. A. Inorg. Chem. 2014, 53, 12372-12377 (Doi 10.1021/Ic501695n).

55. "Sulfur-Oxygenation Enhances Ligand Exchange in Nitrile Hydratase Inspired Ruthenium(II) Complexes" Masitas, C. A.; Mashuta, M. S.; Grapperhaus C. A. ACS Symposium Series, Volume 1152 Biochalcogen Chemistry: The Biological Chemistry of Sulfur, Selenium, and Tellurium, Chapter 4, 2013, pp 71-87.

54. "Reinvestigation of the first structurally characterized metal-coordinated sulfenic acid complex" Chauhan, R.; Mashuta, M. S.; Grapperhaus, C. A. Inorg. Chem. Commun. 2013, 37, 186-188.

53. "Addition of polysubstituted alkenes, aromatic alkynes, and dienes to a metal-stabilized thiyl radical via carbon-sulfur bond formation: Electrochemical, chemical, and computational investigations" Sampson, K. O.; Kumar, D.; Mashuta, M. S.; Grapperhaus, C. A. Inorg. Chim. Acta 2013, 408, 1-8.

52. "Probing the Reactivity and Radical Nature of Oxidized Transition Metal-Thiolate Complexes by Mass Spectrometry" Lu, M.; Campbell, J. L.; Chauhan, R.; Grapperhaus, C. A. ; Chen, H. J. Am. Soc. Mass. Spec. 2013, 24, 502-512.

51. "Bioinspired catalytic nitrile hydration by dithiolato, sulfinato/thiolato, and sulfenato/sulfinato ruthenium complexes" Kumar, D.; Masitas, C. A.; Tran, T. N.; Grapperhaus, C. A. Chem. Commun. 2013, 294–296.

50. "Selective and Reversible Base-Induced Elimination of a Ruthenium Dithioether Yields a Vinyl Metallosulfonium Complex" Chauhan, R.; Mashuta, M. S.; Grapperhaus, C. A. Inorg. Chem. 2012, 51, 7913–7920.

49. "Influence of Sequential Thiolate Oxidation on a Nitrile Hydratase Mimic Probed by Multiedge X-ray Absorption Spectroscopy" Shearer, J.; Callant, P. E.; Masistas, C. A.; Grapperhaus, C. A. Inorg. Chem. 2012, 51, 6032-6045.

48. "Alkyne addition to a metal-stabilized thiyl radical: Carbon-sulfur bond formation between 1-octyne and [Ru(SP)3]+" Ouch, K.; Mashuta, M. S.; Grapperhaus, C. A. Eur. J. Inorg. Chem. 2012, 475-478.

47. "Kinetic study of nickel-thiolate oxygenation by hydrogen peroxide. Implications for nickel-containing superoxide dismutase" Herdt, D. R.; Grapperhaus, C. A. Dalton Trans. 2012, 41, 364-366.

46. "N-(2-formyl-1-methylimidazol-4-yl)-2,2-dimethylpropanamide: A versatile reagent for preparing imidazole-amine ligands with variable second-coordination spheres" Cheruzel, L. E.; Cui, J. L.; Mashuta, M. S.; Grapperhaus, C. A.; Buchanan, R. M. Tetrahedron Lett. 2011, 52, 4771-4774.

45. "Metal-Stabilized Thiyl Radicals as Scaffolds for Reversible Alkene Addition via C-S Bond Formation/Cleavage" Ouch, K.; Mashuta, M. S.; Grapperhaus, C. A. Inorg. Chem. 2011, 50, 9904–9914.

2006 - 2010

44. "Controlled Sulfur Oxygenation of the Ruthenium Dithiolate (4,7-Bis-(2′-methyl-2′-mercaptopropyl)-1-thia-4,7-diazacyclononane)RuPPh3 under Limiting O2 Conditions Yields Thiolato/Sulfinato, Sulfenato/Sulfinato, and Bis-Sulfinato Derivatives" Masitas, C. A.; Kumar, M.; Mashuta, M. S.; Kozlowski, P. M.; Grapperhaus, C. A. Inorg. Chem. 2010, 49, 10875-10881.

43. "Synthesis, Structure, and Solution Properties of [(mim-TASN)FeCl2]+ and Its μ-Oxo Derivative" Cui, J.; Mashuta, M. S.; Buchanan, R. M.; Grapperhaus, C. A. Inorg. Chem. 2010, 49, 10427-10435.

42. "Asymmetric Oxygenation of a Ruthenium Dithiolate Mimics the Mixed Sulfenato/Sulfinato Donor Sets of Nitrile Hydratase and Thiocyanate Hydrolase" Masitas, C. A.; Mashuta, M. S.; Grapperhaus, C. A. Inorg. Chem. 2010, 49, 5344-5346.

41. "Supramolecular Assembly of a Dinuclear Ag(I) Complex with Discreet Ag2S2 Centers" Grapperhaus, C. A.; Cui, J.; Buchanan, R. M.; Mashuta, M. S. Inorg. Chem. Comm. 2009, 12, 1091-1093.

40. "Synthesis and Sulfur Oxygenation of a (N3S)Ni Complex Related to Nickel-Containing Superoxide Dismutase" Mullins, C. S.; Grapperhaus, C. A.; Frye, B. C.; Wood, L. H.; Hay, A. J.; Buchanan, R. M.; Mashuta, M. S. Inorg. Chem. 2009, 48, 9974-9976.

39. "N2S3X-Fe Models of Nitrile Hydratase" O'Toole, M. G.; Grapperhaus, C. A. In Bioinorganic Chemistry, American Chemical Society: Washington DC, 2009, 99-113.

38. "Substrate Binding Preferences and pKa Determinations of a Nitrile Hydratase Model Complex: Variable Solvent Coordination to [(bmmp-TASN)Fe]OTf" O'Toole, M. G.; Bennett, B.; Mashuta, M. S.; Grapperhaus, C. A. Inorg. Chem. 2009, 48, 2300-2308.

37. "Redox-Regulated Ethylene Binding to a Rhenium-Thiolate Complex" Grapperhaus, C. A.; Ouch, K.; Mashuta, M. S. J. Am. Chem. Soc. 2009, 131, 64-65.

36. "Spin-State-Dependent Oxygen Sensitivity of Iron Dithiolates: Sulfur Oxygenation or Disulfide Formation" O'Toole, M. G.; Kreso, M.; Kozlowski, P. M.; Mashuta, M. S.; Grapperhaus, C. A. J. Biol. Inorg. Chem. 2008, 13, 1219-1230.

35. "Hg(II) and Cd(II) Complexes with Mixed Donor Macrocyclic Thioethers: The Oxophobicity of Mercury(II)" Grant, G. J.; Botros, M. E.; Hassler, J. S.; Janzen, D. E.; Grapperhaus, C. A.; O'Toole, M. G.; VanDerveer, D. G. Polyhedron 2008, 27, 3097-3104.

34. "An Experimental and Computational Study of Sulfur-Modified Nucleophilicity in a Dianionic NiN2S2 Complex" Green, K. N.; Brothers, S. M.; Jenkins, R. M.; Carson, C. E.; Grapperhaus, C. A.; Darensbourg, M. Y. Inorg. Chem. 2007, 46, 7536-7544.

33. "Carbon-Sulfur Bond Formation via Alkene Addition to an Oxidized Ruthenium Thiolate" Grapperhaus, C. A.; Venna, K. B.; Mashuta, M. S. Inorg. Chem. 2007, 46, 8044-8050.

32. "{3,3 '-[Ethane-1,2-diylbis(methylimino)]-bis(propane-1-thiolato)}nickel(II)" Grapperhaus, C. A.; O'Toole, M. G.; Mashuta, M. S. Acta Cryst. Section E 2007, 63, M2281-U317.

31. "Singlet Diradical Character of an Oxidized Ruthenium Trithiolate: Electronic Structure and Reactivity" Grapperhaus, C. A.; Kozlowski, P. M.; Kumar, D.; Frye, H. N.; Venna, K. B.; Poturovic, S. Angew. Chem., Int. Ed. Engl. 2007, 46, 4085-4088.

30. "Density Functional Theory Investigations of NiN2S2 Reactivity as a Function of Nitrogen Donor Type and N-H...S Hydrogen Bonding Inspired by Nickel-Containing Superoxide Dismutase" Mullins, C. S.; Grapperhaus, C. A.; Kozlowski, P. M. J. Biol. Inorg. Chem. 2006, 11, 617-625.

29. "Synthesis and Structure of the Tetradeca-Iron(III) Oxide-Alkoxide Cluster [Bu4N]2[Fe14O8(OCH2CH3)20Cl8]" Grapperhaus, C. A.; O'Toole, M. G.; Mashuta, M. S. Inorg. Chem. Comm. 2006, 9, 1204-1206.

28. "Ethyl 1-methylimidazole-2-carboxylate." Frye, B. C.; Mashuta, M. S.; Mullins, C. S.; Grapperhaus, C. A.; Buchanan, R. M. Acta Cryst. Section E 2006, 62, O1548-O1549.

2000 - 2005

27. "Carbon-Sulfur Bond Formation between a Ruthenium-Coordinated Thiyl Radical and Methyl Ketones" Poturovic, S.; Grapperhaus, C. A.; Mashuta, M. S. Angew. Chem., Int. Ed. Engl. 2005, 44, 1883-1887.

26. "Oxygenation of a Ruthenium(II) Thiolate to a Ruthenium(II) Sulfinate Proceeds via Ruthenium(III)" Grapperhaus, C. A.; Poturovic, S.; Mashuta, M. S. Inorg. Chem. 2005, 44, 8185-8187.

25. "Structural comparison of alkylated derivatives of (bmmp-dmed)Ni and (bmmp-dmed)Zn" Grapperhaus, C. A.; Mullins, C. S.; Mashuta, M. S. Inorg. Chim. Acta 2005, 358, 623-632.

24. "Template synthesis of N2S and N3S chelates via alkylation of bis(2-aminoethanethiolato)Ni: sulfur and nitrogen-centered alkylations" Grapperhaus, C. A.; Kreso, M.; Burkhardt, G. A.; Roddy, J. V. F.; Mashuta, M. S. Inorg. Chim. Acta 2005, 358, 123-130.

23. "Structural, spectroscopic, and computational study of an octahedral, non-heme {Fe-NO}6-8 series: Fe(NO)(cyclam-ac)2+/+/0" Serres, R. G.; Grapperhaus, C. A.; Bothe, E.; Bill, E.; Weyhermuller, T.; Neese, F.; Wieghardt, K. J. Am. Chem. Soc. 2004, 126, 5138-5153.

22. "Electrochemical investigations of the [tris(2-(diphenylphosphino)thiaphenolato)ruthenate(II)] monoanion reveal metal- and ligand-centered events: Radical, reactivity, and rate" Grapperhaus, C. A.; Poturovic, S. Inorg. Chem. 2004, 43, 3292-3298.

21. "Synthesis and oxygenation of a nickel(II) and zinc(II) dithiolate: An experimental and theoretical comparison" Grapperhaus, C. A.; Mullins, C. S.; Kozlowski, P. M.; Mashuta, M. S. Inorg. Chem. 2004, 43, 2859-2866.

20. "Hydrogen-bond networks in the mono- and diprotonated cyclic diamine [9]aneN2S." Grapperhaus, C. A.; Li, M.; Gibson, E. R.; Mashuta, M. S. J. Chem. Cryst. 2004, 34, 5-11.

19. "Synthesis and characterization of N2S3X-Fe models of iron-containing nitrile hydratase." Grapperhaus, C. A.; Li, M.; Patra, A. K.; Poturovic, S.; Kozlowski, P. M.; Zgierski, M. Z.; Mashuta, M. S. Inorg. Chem. 2003, 42, 4382-4388.

18. "cis-Dioxocyclam" Mashuta, M. S.; Pimenov, K. V.; Grapperhaus, C. A. Acta Cryst. Section C 2002, 58, O226-O227.

17. "Unique reactivity of a tetradentate N2S2 complex of nickel: Intermediates in the production of sulfur oxygenates." Kaasjager, V. E.; Bouwman, E.; Gorter, S.; Reedijk, J.; Grapperhaus, C. A.; Reibenspies, J. H.; Smee, J. J.; Darensbourg, M. Y.; Derecskei-Kovacs, A.; Thomson, L. M. Inorg. Chem. 2002, 41, 1837-1844.

16. "Dichloromethane alkylates a trithiolato-ruthenium complex to yield a methylene-bridged thioether core. Synthesis and structural comparison to the thiolato-ruthenium precursor" Grapperhaus, C. A.; Poturovic, S.; Mashuta, M. S. Inorg. Chem. 2002, 41, 4309-4311.

15. "First {Fe-NO}6 complex with an N2S3Fe-NO core as a model of NO-inactivated iron-containing nitrile hydratase. Are thiolates and thioethers equivalent donors in low-spin iron complexes?" Grapperhaus, C. A.; Patra, A. K.; Mashuta, M. S. Inorg. Chem. 2002, 41, 1039-1041.

14. "1,5-Bis(benzothiazolyl)-3-thiapentane and its asymmetric dinuclear Ag(I) complex with three distinct intermolecular-stacking interactions" Grapperhaus, C. A.; Li, M.; Mashuta, M. S. Chem. Commun. 2002, 1792-1793.

13. "Subtle bite-angle influences on N2S2Ni complexes" Smee, J. J.; Miller, M. L.; Grapperhaus, C. A.; Reibenspies, J. H.; Darensbourg, M. Y. Inorg. Chem. 2001, 40, 3601-3605.

12. "Synthetic models of nitrile hydratase" Grapperhaus, C. A.; Patra, A. K.; Poturovic, S. J. Inorg. Biochem. 2001, 86, 240-240.

11. "Molecular and electronic structure of [(MnVN(cyclam-acetato)]PF6. A combined experimental and DFT study" Grapperhaus, C. A.; Bill, E.; Weyhermuller, T.; Neese, F.; Wieghardt, K. Inorg. Chem. 2001, 40, 4191-4198.

10. "Mononuclear (nitrido)iron(V) and (oxo)iron(IV) complexes via photolysis of [(cyclam-acetato)FeIII(N3)]+ and ozonolysis of [(cyclam-acetato)FeIII(O3SCF3)]+ in water/acetone mixtures" Grapperhaus, C. A.; Mienert, B.; Bill, E.; Weyhermuller, T.; Wieghardt, K. Inorg. Chem. 2000, 39, 5306-5317.

9. "Correlation of electrochemistry, nucleophilicity and density functional calculations of the cis-dithiolate (bme*-daco)Ni" Bellefeuille, J. A.; Grapperhaus, C. A.; Derecskei-Kovacs, A.; Reibenspies, J. H.; Darensbourg, M. Y. Inorg. Chim. Acta 2000, 300, 73-81.

8. "Ozone oxidation of iron(III) in a monofunctionalized cyclam: Spectroscopic characterization of high valent iron species" Grapperhaus, C. A.; Bill, E.; Wieghardt, K. J. Inorg. Biochem. 1999, 74, 146-146.

Before 2000

7. "Synthesis and dimer cleavage reactions of the N2S thiolate bridged dimer [(mmp-dach)2Ni2]Cl2" Grapperhaus, C. A.; Bellefeuille, J. A.; Reibenspies, J. H.; Darensbourg, M. Y. Inorg. Chem. 1999, 38, 3698-3703.

6. "Methylation of tethered thiolates in [(bme-daco)Zn]2 and [(bme-daco)Cd]2 as a model of zinc sulfur-methylation protein" Grapperhaus, C. A.; Tuntulani, T.; Reibenspies, J. H.; Darensbourg, M. Y. Inorg. Chem. 1998, 37, 4052-4058.

5. "Oxygen capture by sulfur in nickel thiolates" Grapperhaus, C. A.; Darensbourg, M. Y. Acc. Chem. Res. 1998, 31, 451-459.

4. "1,5-Diazacyclooctane, Pendant Arm Thiolato Derivatives and [(N,N’-bis(2-mercaptoethyl)-1,5-diazacyclooctanato]Nickel(II)" Mills, D. K.; Font, I.; Farmer, P. J.; Hsiao, Y. M.; Tuntulani, T.; Buonomo, R. M.; Goodman, D. C.; Musie, G.; Grapperhaus, C. A.; Maguire, M. J.; Lai, C. H.; Hatley, M. L.; Smee, J. J.; Bellefeuille, J. A.; Darensbourg, M. Y. Inorg. Synth. 1998, 37, 4052-4058.

3. "Alkylation-induced O-atom rearrangement in nickel S-oxygenates" Bellefeuille, J. A.; Grapperhaus, C. A.; Buonomo, R. M.; Reibenspies, J. H.; Darensbourg, M. Y. Organometallics 1998, 17, 4813-4821.

2. "Singlet oxygen and the production of sulfur oxygenates of nickel(II) and palladium(II) thiolates" Grapperhaus, C. A.; Maguire, M. J.; Tuntulani, T.; Darensbourg, M. Y. Inorg. Chem. 1997, 36, 1860-1866.

1. "Template effect for O2 addition across cis-sulfur sites in nickel dithiolates" Grapperhaus, C. A.; Darensbourg, M. Y.; Sumner, L. W.; Russell, D. H. J. Am. Chem. Soc. 1996, 118, 1791-1792.